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當(dāng)前位置：西安齊岳生物科技有限公司>>技術(shù)文章>>二氯酞菁錫（IV） Tin（IV） 酞菁分子材料
二氯酞菁錫(IV) Tin(IV) Phthalocyanine Dichloride 18253-54-8
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二氯酞菁錫(Ⅳ)的合成研究
以鄰苯二甲酸酐、尿素、六水合四氯化錫為原料,氯化銨為催化劑,采用固法合成二氯酞菁錫(Ⅳ),并用元素分析、IR、XPS、XRD進(jìn)行表征?？疾炝朔磻?yīng)物配比、催化劑、反應(yīng)溫度和時(shí)間對(duì)產(chǎn)率的影響,尋找出合成條件為n(鄰苯二甲酸酐):n(尿素):n(六水合氯化錫)=5:15:1,以鉬酸銨和氯化銨為催化劑,加入反應(yīng)器中,用水蒸汽冷凝回流,在150℃反應(yīng)1h后,升溫到260℃,繼續(xù)反應(yīng)1h,收率70.70%。
室溫下銅表面上單個(gè)二氯酞菁錫分子的可控操縱研究
基于室溫下單個(gè)二氯酞菁錫分子在銅(100)表面上具有兩種等價(jià)的吸附取向,利用高真空掃描隧道顯微鏡(STM)針尖,通過Z(V)縱向操縱模式可對(duì)單個(gè)二氯酞菁錫分子的吸附取向進(jìn)行原位切換,從而實(shí)現(xiàn)了對(duì)該分子吸附取向的調(diào)控;而且通過對(duì)單個(gè)二氯酞菁錫分子不同的部位進(jìn)行縱向操縱,還能夠驅(qū)使單個(gè)二氯酞菁錫分子在銅(100)表面做定向運(yùn)動(dòng),其運(yùn)動(dòng)距離為表面的銅原子晶格的倍數(shù)?；诳v向操縱時(shí)掃描隧道顯微鏡針尖與標(biāo)記分子之間的距離的分析,認(rèn)為針尖與分子間的排斥力是實(shí)現(xiàn)該操縱作用力的主要來源。利用該操作方式不構(gòu)建了納米尺度的分子存儲(chǔ)原型器件,而且組裝了小尺寸的南昌大學(xué)英文校名縮寫。通過該可控操縱,研究了分子排列形式對(duì)單個(gè)二氯酞菁錫分子的分子取向的影響。實(shí)驗(yàn)結(jié)果揭示出位于三分子體系中間的分子的吸附取向可藉由其他兩個(gè)分子的吸附取向進(jìn)行調(diào)控。理論計(jì)算進(jìn)一步了該非接觸式調(diào)控來源于其近鄰距離分子吸附狀態(tài)對(duì)單個(gè)分子的吸附能量的影響。基于該發(fā)現(xiàn),通過不同分子排列方式實(shí)現(xiàn)了對(duì)單個(gè)分子運(yùn)動(dòng)狀態(tài)的調(diào)控和在納米尺度下的分子集體運(yùn)動(dòng)。也通過的分子排列構(gòu)型,構(gòu)建了由四個(gè)分子構(gòu)成的分子邏輯門原型器件。
| 產(chǎn)品名稱 | 別名 | 英文名稱 | cas |
| 酞菁二鋰 | Phthalocyanine Dilithium | 25510-41-2 | |
| 5,10,15,20-四苯基-21H,23H-卟啉鋅(II) 鋅(II)TPP | 四苯基卟啉鋅(II) | 5,10,15,20-Tetraphenyl-21H,23H-porphine Zinc(II) Zinc(II) TPP | 14074-80-7 |
| 2,3,7,8,12,13,17,18-八乙基卟啉 | 2,3,7,8,12,13,17,18-八乙基-21H,23H-卟吩 | 2,3,7,8,12,13,17,18-Octaethylporphyrin | 2683-82-1 |
| 二氯酞菁錫(IV) | 酞菁二氯化錫(IV) | Tin(IV) Phthalocyanine Dichloride | 18253-54-8 |
| 酞菁二鈉 | Disodium Phthalocyanine | 25476-27-1 | |
| 5,10,15,20-四(2,4,6-*苯基)卟啉 | 5,10,15,20-四(2,4,6-*苯基) -21H,23H-卟吩 | 5,10,15,20-Tetrakis(2,4,6-trimethylphenyl)porphyrin | 56396-12-4 |
| 5,9,14,18,23,27,32,36-八丁氧基-2,3-萘酞菁銅(II) 銅(II)-5,9,14,18,23,27,32,36-八丁氧基-2,3-萘酞菁 | 5,9,14,18,23,27,32,36-Octabutoxy-2,3-naphthalocyanine Copper(II) | Copper(II) 5,9,14,18,23,27,32,36-Octabutoxy-2,3-naphthalocyanine | 155773-67-4 |
| 四苯基卟啉氯化鐵(III) | 5,10,15,20-四苯基-21H,23H-卟啉氯化鐵(III) 5,10,15,20-Tetraphenyl-21H,23H-porphine Iron(III) Chloride | Iron(III) Tetraphenylporphyrin Chloride | 16456-81-8 |
| 酞菁鐵(II) (升華提純) | Phthalocyanine Iron(II) (purified by sublimation) | Iron(II) Phthalocyanine (purified by sublimation) | 132-16-1 |
| [5-[雙(4-己基苯基)氨基]-15-[2-(4-羧基苯基)乙炔基]-10,20-雙(3,5-二-叔丁基苯基)卟啉]合鋅(II) | YD2 | [5-[Bis(4-hexylphenyl)amino]-15-[2-(4-carboxyphenyl)ethynyl]-10,20-bis(3,5-di-tert-butylphenyl)porphyrinato]zinc(II) | 1201915-91-4 |
| 酞菁錫(II) | Phthalocyanine Tin(II) | Tin(II) Phthalocyanine | 15304-57-1 |
| 酞菁鎂(II) | Phthalocyanine Magnesium(II) | Magnesium(II) Phthalocyanine | 1661-03-6 |
| 5,10,15,20-四(2,6-二)卟吩 | 5,10,15,20-四(2,6-二)卟啉 | 5,10,15,20-Tetrakis(2,6-dichlorophenyl)porphyrin | 37083-37-7 |
| 2,3,7,8,12,13,17,18-八氟-5 ,10,15,20-四(五氟苯基)卟啉 | 全氟-5,10,15,20-四苯基-21H,23H-卟啉 | 2,3,7,8,12,13,17,18-Octafluoro-5,10,15,20-tetrakis(pentafluorophenyl)porphyrin | 121399-88-0 |
| 酞氰化鋅 (升華提純) | 酞菁鋅 | Zinc Phthalocyanine (purified by sublimation) | 14320-04-8 |
| 5,15-二苯基卟啉 | 5,15-二苯基-21H,23H-卟吩 | 5,15-Diphenylporphyrin | 22112-89-6 |
| 酞菁鉛(II) | Phthalocyanine Lead(II) | Lead(II) Phthalocyanine | 15187-16-3 |
| 酞菁鈷(II) (升華提純) | Cobalt(II) Phthalocyanine (purified by sublimation) | 3317-67-7 | |
| 2,3,9,10,16,17,23,24-八氟酞菁銅(II) (升華純化) | 2,3,9,10,16,17,23,24-Octafluorophthalocyanine Copper(II) (purified by sublimation) F8CuPc (purified by sublimation) | Copper(II) 2,3,9,10,16,17,23,24-Octafluorophthalocyanine (purified by sublimation) | 148651-60-9 |
| 2,9,16,23-四叔丁基酞菁銅(II) | 4,4',4',4'-四叔丁基酞菁銅 | Copper(II) 2,9,16,23-Tetra-tert-butylphthalocyanine | 39001-64-4 |
| 四苯基卟啉鈷(II) | 5,10,15,20-四苯基-21H,23H-卟吩鈷(II) TPP鈷(II) | Cobalt(II) Tetraphenylporphyrin | 14172-90-8 |
| 四苯基卟啉銅(II) | 5,10,15,20-四苯基-21H,23H-卟啉銅(II) 銅(II)TPP | Copper(II) Tetraphenylporphyrin | 14172-91-9 |
| 酞菁氯化鋁 | 鋁酞菁 | Phthalocyanine Chloroaluminum | 14154-42-8 |
| 1,2,3,4,8,9,10,11,15,16,17,18,22,23,24,25-十六氟酞菁銅(II) (升華提純) | F16CuPc (purified by sublimation) | 1,2,3,4,8,9,10,11,15,16,17,18,22,23,24,25-Hexadecafluorophthalocyanine Copper(II) (purified by sublimation) | 14916-87-1 |
| 酞菁藍(lán) | 酞菁銅(II),90%（β型） | Phthalocyanine Blue | 147-14-8 |
| 顏料藍(lán)16 (升華提純) | Pigment Blue 16 (purified by sublimation) | Phthalocyanine (purified by sublimation) | 574-93-6 |
| 5,10,15,20-四(4-羧基甲氧苯基)-卟啉 | 5,10,15,20-四(4-羧基甲氧苯基)-21H,23H-卟吩 | 5,10,15,20-Tetrakis(4-carboxymethyloxyphenyl)porphyrin | 127812-08-2 |
| 5,10,15,20-四(對(duì)甲苯基)卟啉 | 5,10,15,20-四(4-甲苯基)卟啉 | 5,10,15,20-Tetrakis(p-tolyl)porphyrin | 14527-51-6 |
| 5,10,15,20-四(4-羥苯基)卟啉 | 5,10,15,20-四(4-羥苯基)-21H,23H-卟吩 | 5,10,15,20-Tetrakis(4-hydroxyphenyl)porphyrin | 51094-17-8 |
| 5,10,15,20-四(3,5-二甲氧苯基)卟啉 | 5,10,15,20-四(3,5-二甲氧苯基)-21H,23H-卟吩 | 5,10,15,20-Tetrakis(3,5-dimethoxyphenyl)porphyrin | 74684-34-7 |
| 內(nèi)消旋-四苯基卟吩 | meso-Tetraphenylchlorin | 2669-65-0 | |
| meso-四(4-羧基苯基)卟吩四甲酯 | 5,10,15,20-四(4-甲氧羰基苯基)卟啉 | 5,10,15,20-Tetrakis(4-methoxycarbonylphenyl)porphyrin | 22112-83-0 |
| 5,10,15,20-四(4-氨基苯基)卟啉 | 5,10,15,20-四(4-氨基苯基)-21H,23H-卟吩 | 5,10,15,20-Tetrakis(4-aminophenyl)porphyrin | 22112-84-1 |
| 5-(4-羧苯基)-10,15,2-三苯基卟啉 | 5-(4-羧苯基)-10,15,2-三苯基-21H,23H-卟吩 | 5-(4-Carboxyphenyl)-10,15,20-triphenylporphyrin | 95051-10-8 |
| 5,10,15,20-四(五氟苯基)卟啉 | 5,10,15,20-四(五氟苯基)-21H,23H-卟吩 | 5,10,15,20-Tetrakis(pentafluorophenyl)porphyrin | 25440-14-6 |
| 5,10,5,20-四(3,5-二羥苯基)卟啉 | 5,10,5,20-四(3,5-二羥苯基) -21H,23H-卟吩 | 5,10,15,20-Tetrakis(3,5-dihydroxyphenyl)porphyrin | 145764-54-1 |
| 酞菁綠G | 顏料綠 7 | Pigment Green 7 | 1328-53-6 |
| 5,15-雙(苯乙炔基)-10,20-雙[(三異丙基硅烷基)乙炔基]卟吩]]合鎂(II) | [5,15-Bis(phenylethynyl)-10,20-bis[(triisopropylsilyl)ethynyl]porphyrinato]magnesium(II) | 1397288-30-0 | |
| 錫(IV) 2,3-二氯化萘酞菁 | 二氯(2,3-萘酞氰基)錫(IV) | Tin(IV) 2,3-Naphthalocyanine Dichloride | 26857-61-4 |
| 5,10,15,20-四(4-甲氧苯基)-21H,23H-卟吩 | 5,10,15,20-四(4-甲氧苯基)卟啉 | 5,10,15,20-Tetrakis(4-methoxyphenyl)porphyrin | 22112-78-3 |
| 氧鈦酞菁 (升華提純) | 酞菁氧鈦/氧化(酞菁)鈦 | Titanyl Phthalocyanine (purified by sublimation) | 26201-32-1 |
| 四苯基卟吩 | Tetraphenylporphine (Chlorin free) TPP (Chlorin free) | Tetraphenylporphyrin (Chlorin free) | 917-23-7 |
| 5-(4-甲氧羰基苯基)-10,15,2-三苯基卟吩 | 5-(4-Carbomethoxyphenyl)-10,15,20-triphenylporphyrin | 5-(4-Methoxycarbonylphenyl)-10,15,20-triphenylporphyrin | 119730-06-2 |
| [5,10,15,20-四(4-甲氧苯基)卟啉]合鈷(II) | [5,10,15,20-四(4-甲氧苯基)-21H,23H-卟吩]合鈷(II) 卟啉鈷 | [5,10,15,20-Tetrakis(4-methoxyphenyl)porphyrinato]cobalt(II) | 28903-71-1 |
| 5,10,15,20-四(4-吡啶基)卟啉 | 5,10,15,20-四(4-吡啶基)-21H,23H-卟啉 | 5,10,15,20-Tetra(4-pyridyl)porphyrin | 16834-13-2 |
| 四(4-羧苯基)卟吩 | TCPP [=四(4-羧苯基)卟吩] [銅和鎘用高靈敏分光光度試劑][用于以HPLC進(jìn)行的金屬同時(shí)測(cè)定] | Tetrakis(4-carboxyphenyl)porphyrin | 14609-54-2 |
| 5,10,15,20-四(4-磺苯基)卟啉 四苯基卟啉四磺酸 | TPPS (=四苯基卟啉四磺酸水合物) | 5,10,15,20-Tetrakis(4-sulfophenyl)porphyrin Tetraphenylporphyrin Tetrasulfonic Acid | 35218-75-8 |
| 二氰基吡嗪類&類似物 [酞菁砌塊] | |||
| 2-氨基-4,5-二氰基-1H-咪唑 | 2-氨基-4,5-咪唑二甲腈 | 2-Amino-4,5-dicyaH-imidazole | 40953-34-2 |
| 1,4,5,6-四氫-5,6-二氧-2,3-二氰基吡嗪 | 1,4,5,6-四氫-5,6-二氧-2,3-吡嗪二甲腈 | 1,4,5,6-Tetrahydro-5,6-dioxo-2,3-pyrazinedicarbonitrile | 36023-64-0 |
| 5,6-二氨基-2,3-二氰基吡嗪 | 2,3-二氰基-5,6-二氨基吡嗪 | 5,6-Diamino-2,3-dicyanopyrazine | 36023-58-2 |
| 2,3-二氰基-5-甲基吡嗪 | 5-Methyl-2,3-pyrazinedicarbonitrile | 2,3-Dicyano-5-methylpyrazine | 52197-12-3 |
| 吡啶-2,3-二甲腈 | 2,3-二氰基吡啶 | Pyridine-2,3-dicarbonitrile | 17132-78-4 |
| 2,3-二氰基吡嗪 | 吡嗪-2,3-二甲腈 | 2,3-Dicyanopyrazine | 13481-25-9 |
| 4,5-二氰基咪唑 | DCI/4,5-二氰咪唑 | 4,5-Dicyanoimidazole | 1122-28-7 |
| 5,6-二氯-2,3-二氰基吡嗪 | 5,6-Dichloro-2,3-pyrazinedicarbonitrile | 5,6-Dichloro-2,3-dicyanopyrazine | 56413-95-7 |
| 2,3-二氰基-5-氨基-6-氯吡嗪 | 5-氨基-6-氯-2,3-二氰基吡嗪 | 5-Amino-6-chloro-2,3-dicyanopyrazine | 56413-96-8 |
| 鄰苯二甲腈類 [酞菁砌塊] | |||
| 4-硝基鄰苯二甲腈 | 1,2-二氰基-4-硝基苯 | 4-Nitrophthalonitrile | 31643-49-9 |
| 1,3-二亞氨基異吲哚啉 | 1,3-Diiminoisoindoline | 57500-34-2 | |
| 4-酞腈 | 1,2-二氰基-4-苯 | 4-Iodophthalonitrile | 69518-17-8 |
| 3-硝基鄰苯二甲腈 | 1,2-二氰基-3-硝基苯 | 3-Nitrophthalonitrile | 51762-67-5 |
| 4-(4-α-異丙苯基苯氧基)苯二甲腈 | 2-[4-(3,4-Dicyanophenoxy)phenyl]-2-phenylpropane | 4-(4-α-Cumylphenoxy)phthalonitrile | 83482-57-9 |
| 4-戊氧基苯二甲腈 | 4-戊氧基鄰苯二甲腈 | 4-Pentyloxyphthalonitrile | 106943-83-3 |
| 4-溴鄰苯二甲腈 | 4-溴-1,2-二氰基苯 | 4-Bromophthalonitrile | 70484-01-4 |
| 4-正丁氧基-1,2-二氰苯 | 4-丁氧基鄰苯二甲腈 | 4-Butoxyphthalonitrile | 81560-32-9 |
| 4-己氧基苯二甲腈 | 1,2-Dicyano-4-hexyloxybenzene | 4-Hexyloxyphthalonitrile | 104949-82-8 |
| 4-丙氧基鄰苯二甲腈 | 4-丙氧基苯二甲腈 | 4-Propoxyphthalonitrile | 106144-18-7 |
| 4-氨基鄰苯二甲腈 | 3,4-二氰基苯胺 | 4-Aminophthalonitrile | 56765-79-8 |
| 1,2-二氰基-4-氟苯 | 4-氟鄰苯二腈 | 4-Fluorophthalonitrile | 65610-14-2 |
| 4,5-二氟酞腈 | 1,2-二氰基-4,5-二氟苯 | 4,5-Difluorophthalonitrile | 134450-56-9 |
| 4,5-二氨基酞腈 | 1,2-二氨基-4,5-二氰基苯 | 4,5-Diaminophthalonitrile | 129365-93-1 |
| 4-(2',6'-二甲基苯氧基)鄰苯二甲腈 | 1,2-二氰基-4-(2',6'-二甲基苯氧基)苯 | 4-(2',6'-Dimethylphenoxy)phthalonitrile | 221302-75-6 |
| 4,5-二氯鄰苯二甲腈 | 1,2-二氯-4,5-二氰基苯 | 4,5-Dichlorophthalonitrile | 139152-08-2 |
| 鄰苯二甲腈 | 1,2-二氰基苯 | Phthalonitrile | 91-15-6 |
| 全氯鄰苯二甲腈 | 四氯鄰苯二甲腈 | Tetrachlorophthalonitrile | 1953-99-7 |
| 4-叔丁基鄰苯二甲腈 | 4-叔丁基-1,2-二氰基苯 | 4-tert-Butylphthalonitrile | 32703-80-3 |
| 四氟鄰苯二甲腈 | 3,4,5,6-四氟鄰苯二甲腈 | Tetrafluorophthalonitrile | 1835-65-0 |
| 4-羥基鄰苯二甲腈 | 3,4-二氰基苯酚 | 4-Hydroxyphthalonitrile | 30757-50-7 |
| 1,2-Dicyano-4-dodecyloxybenzene | 4-十二烷氧基鄰苯二甲腈 | 4-Dodecyloxyphthalonitrile | 161082-75-3 |
| 1,2,4,5-四氰基苯 | 1,2,4,5-苯四甲腈 | 1,2,4,5-Tetracyanobenzene | 712-74-3 |
| 2,3-二氰基對(duì)苯二酚 | 3,6-二羥基鄰苯二甲腈 2,3-二氰基羥基醌 3,6-二羥基鄰苯二腈 3,6-二羥基鄰苯二甲氰 2,3-二氰基氫醌 | 2,3-Dicyanohydroquinone | 4733-50-0 |
| 萘二甲腈類 [酞菁砌塊] | |||
| 1,2-萘二甲腈 | 1,2-二氰基萘 | 1,2-Naphthalenedicarbonitrile | 19291-76-0 |
| 1,3-二亞氨基苯并[f]異吲哚啉 | 1,3-Diiminobenz[f]isoindoline | 65558-69-2 | |
| 2,3-二氰基-6-硝基萘 | 2,3-Dicyano-6-nitronaphthalene | 184026-06-0 | |
| 2,3-二溴-6,7-二氰基萘 | 6,7-Dibromonaphthalene-2,3-dicarbonitrile | 2,3-Dibromo-6,7-dicyanonaphthalene | 74815-81-9 |
| 2,3-二氰基-1,4-二羥基-5-硝基萘 | 2,3-二氰基-5-硝基-1,4-萘二醇 | 2,3-Dicya,4-dihydroxy-5-nitronaphthalene | 4655-62-3 |
| 6-溴-2,3-二氰基萘 | 6-溴萘-2,3-二甲腈 | 6-Bromo-2,3-dicyanonaphthalene | 70484-02-5 |
| 2,3-二氰基萘 | 2,3-萘二甲腈 | 2,3-Dicyanonaphthalene | 22856-30-0 |
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